Reference Guide #3: Beilsteins Handbuch der Organischen Chemie

Simplified Overview and Suggestions for Use

Beilstein[ QD251.B4 Ref. Rm.] is a powerful tool for accessing information in all areas of organic chemistry. The goals of this compilation are:
1. to supply condensed, verified and accurate data on the composition, preparation, structure, properties and analysis of all organic compounds which are reported in reliable scientific literature
2. give complete references to the original sources, such as journal articles.
In order to use Beilstein it is necessary to know in general terms the way it is organized, the conventions used to summarize information, and some basic facts about organic compounds and chemical nomenclature.

Basic Facts About Organic Compounds and Chemical Nomenclature

Compounds
Organic compounds include all compounds of the element carbon, except carbonates and some of their relatives, such as CO2, which are traditionally considered inorganic. All compounds that do not contain carbon are inorganic . Formulas of organic compounds are extremely numerous and may represent very complex molecules, involving rings, side chains, etc. The most important distinction is between those of cyclic (with rings) and acyclic (no rings) formulas. Cyclic organic compounds can be homocyclic (the ring atoms are exclusively carbon) or heterocyclic (the ring atoms include elements other than carbon, e.g. N, S, O, etc.)
Formulas
Compounds are represented by formulas made up of the symbols of the elements present and numerals indicating the number of atoms of the same element or the numbers of repetitions of some combinations of atoms ( called groups or radicals). There are two main classes of formulas in the literature. The molecular formula gives only the elements and the number of atoms of each of them in the molecule. The molecular formula for ethanol (ethyl alcohol), for instance, is C2H6O. Different compounds may have the same molecular formula; e.g. that of methyl ether is also C2H6O. The structural formula indicates how the atoms are arranged in the molecule. For instance, the structural formula of ethanol is C2 H5OH and that of methyl ether is CH3OCH3.

Outline of Beilstein's Organization


The collection is divided into one basic series and five succeeding supplementary series with the following designations:

• Basic series: H ( up to 1910).
• Supplementary series: EI, EII, EIII, EIII/EIV, EIV and EV at 10-year intervals (1910 - 1979).

Each series is made up of 27 volumes, many of which comprise several physically distinct parts. Individual compounds are arranged in different volumes according to a complex scheme based on the groups of atoms included in each compound and on whether the compounds are acyclic, isocyclic or heterocyclic .

The Beilstein Guide [QD251.B43W44 1976 Ref. Desk] has tables showing the dates, contents and color codes of the volumes. Each volume contains a Name Index and a Formula Index, and there are several cumulative indexes in both categories. The original language is German, but the text is in English beginning with the fifth supplementary series. The lowest level of classification is the system number which groups together compounds of similar structural characteristics. Series EV starts with volume 17; volumes 1-16, which refer to well-known compounds, are omitted.

In the earlier series journal citations are given by means of the abbreviated title, volume and pages. The full titles corresponding to the abbreviations are given in the first volume of each series. A chart at the beginning of the first volume of the series provides a concordance of volumes and years.

Finding Information in Beilstein


For most practical purposes there are three main ways of searching:
1. direct search of the volumes using the rules of the Beilstein system as explained in the Beilstein Guide [QD251.B43W44 1976 Ref. Desk].
2. indirect search using the various indexes. In most cases the simplest procedure is to use the Molecular Formula Index.
3. direct search using the reference number (volume + page number) for the compound as found in the Aldrich Catalog[(TP202.A38 1998-99 Ref. Desk] or in other sources. In many cases this is the simplest and fastest way to access Beilstein's information on a given compound. If a compound is not found in the Aldrich Catalog one can often find a similar compound (similar structural formula) in the catalog and in many cases the required compound will be found near that one in Beilstein.

Bibliography

How to use Beilstein : Beilstein handbook of organic chemistry. Beilstein Institute. Frankfurt/Main, 1978 [QD251.B43B434 1978 Ref. Rm.] This 34-page booklet is shelved next to theHandbuch.
The Beilstein guide : a manual for the use of Beilsteins Handbuch der Organischen Chemie. Oskar Weissbach [translated by H. M. R.Hoffmann]. [QD251.B43W44 1976 Ref. Desk]
The Beilstein system : strategies for effective searching. Stephen R. Heller, editor. Washington, DC: American Chemical Society, 1998. [QD251.B417 1998 Ref. Rm.]

Other Reference Guides

Guide #1: History of Science and Technology
Guide #2: Units, Dimensions, Conversions and Formulas
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